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Tetrafluoromethane (CF4)

Tetrafluoromethane (CF4) is a colorless, nonflammable, noncorrosive gas. It is normally compressed and shipped at high pressure.

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Tetrafluoromethane

Formula: CF4

CAS No: 75-73-0

Tetrafluoromethane (CF4) is a colorless, non-flammable fluorocarbon gas widely used in semiconductor manufacturing and plasma processing. It is valued for its ability to generate fluorine radicals under plasma conditions, enabling efficient etching of silicon-based materials.

In semiconductor fabrication, CF4 is used for plasma etching of silicon, silicon dioxide, and silicon nitride. Its stability and performance in plasma systems support consistent process control and high-throughput manufacturing.

Applications include:

  • Used in plasma etching of silicon, silicon dioxide, and silicon nitride.
  • Applied in semiconductor manufacturing and microelectronics processing.
  • Enables removal of dielectric and silicon-based materials.
  • Used in surface treatment and plasma cleaning processes.
  • Applied in specialty fluorination and research applications.

EFC Gases & Advanced Materials supplies high-purity tetrafluoromethane with tight control of moisture and critical impurities to ensure consistent performance in demanding applications.

Applications
Specifications
Further Specifications
Cylinder Sizes
  • Etch silicon, SiO₂, and Si₃N₄.
  • Support semiconductor manufacturing.
  • Remove dielectric materials.
  • Clean and treat surfaces with plasma.
  • Use in fluorination and research.
Purity Grade 3.5 Grade 4 Grade 4.5 Grade 5
Purity Specifications 99.95% 99.99% 99.995% 99.999%
Nitrogen < 400 ppmv < 60 ppmv < 30 ppmv < 5 ppmv
Oxygen < 100 ppmv <20 ppmv < 5 ppmv < 1 ppmv
Carbon Monoxide < 20 ppmv < 5 ppmv < 1 ppmv < 0.5 ppmv
Carbon Dioxide < 10 ppmv < 5 ppmv < 1 ppmv < 2 ppmv
Moisture < 10 ppmv < 5 ppmv < 5 ppmv < 1 ppmv
Halocarbon 116 < 1 ppmv
Other Halocarbons < 50 ppmv < 5 ppmv < 5 ppmv
Hydrocarbons < 1 ppmv
Acidity < 0.1 ppm/w < 0.1 ppm/w < 0.1 ppm/w
Chemical & Physical Properties
Molecular Weight 88.01
Specific Volume 4.39 cu.ft/lb
Pressure @ 70° F 23.5 psig
Valve Outlet CGA 580 CGA 320
Shipping Information
DOT Name Tetrafluoromethane
Hazard Class 2.2
DOT No. UN 1982
DOT Label Green, Non-Flammable Gas B
CAS No. 75-73-0
Cylinder Size Fill Weight (lb)
440L/Y-Ton 700
49L/Size 300 72
44L/Size 200 70
16L/Size 80 25
7L/Size 35 11

Moisture level guaranteed only when EFC Gases & Advanced Materials prepares the cylinders.
All concentrations are on a mol/mol basis unless otherwise stated. Product sold on the basis of total impurities. Individual impurities may vary slightly.